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Updated: Jul 9, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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サイクロ[16]炭素の振動によって誘発される芳香性の逆転

Igor Rončević1, Freddie J Leslie1, Max Rossmannek2

  • 1Department of Chemistry, Oxford University, Chemistry Research Laboratory, Oxford OX1 3TA, United Kingdom.

Journal of the American Chemical Society
|December 1, 2023
PubMed
まとめ

サイクロ[16]炭素 (C16) の芳香性の逆転は,ケキュレ振動に沿った幾何学的変化により,反対のπ系電流につながったことが観察された. この発見は,固有の分子特性としての芳香性に関する伝統的な見解に異議を唱えます.

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