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Updated: Jul 9, 2025

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
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Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine

Published on: June 13, 2022

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アトロポスペシフィックカスケードによる (+) -エウフォリカニンAの総合成

Moritz J Classen1, Bilal Kicin1, Vincent A P Ruf1

  • 1Department of Chemistry and Applied Biosciences, Laboratory of Organic Chemistry, ETH Zürich, 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|December 5, 2023
PubMed
まとめ

インゲナンの誘導体であるディターペノイドである (+) - ユーフォリカニンAの全合成が達成された. アルドール添加,ヘミケタル形成,およびセミピナコール再配置を含む新しいワンポットシーケンスにより,複雑な骨格が効率的に構築されました.

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