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Updated: Jul 9, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

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塩基媒介における水素酸化反応の優れた性能に向けた3nm以下のPt@Ru

Fei Yang1,2,3, Yian Wang2, Yingdan Cui2

  • 1Eastern Institute for Advanced Study, Eastern Institute of Technology, Ningbo 315200, Zhejiang, China.

Journal of the American Chemical Society
|December 6, 2023
PubMed
まとめ

研究者らは,シンプルな浸潤法を使用して,3nm以下のPt@Ruコアシェルナノ粒子を開発した. これらの高度な電気触媒は,アニオン交換膜燃料電池 (AEMFC) の水素酸化反応運動を大幅に高めます.

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Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance

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Reduction of Alkenes: Catalytic Hydrogenation

Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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