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Updated: Jul 6, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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ディヒドロフェナントレンオープンシェルシングレットジラジカルとマロリー光回転反応におけるその役割

Elliott B Hulley1, Edward L Clennan1

  • 1Department of Chemistry, University of Wyoming, Laramie, Wyoming 82071, United States.

Journal of the American Chemical Society
|January 2, 2024
PubMed
まとめ

計算による研究は,マロリー光循環における二酸化フェナントレンの中間物質が,閉殻または開殻のダイラジカルである可能性があることを示している. アロマティック性はこれらのダイラジカル形式を安定させる.

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The simplest example of a diene is 1,3-butadiene, an acyclic conjugated π system. At room temperature, the molecule exists as a mixture of s-cis and s-trans conformers by virtue of rotation around the carbon–carbon single bond. Although the s-trans isomer is...
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