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Updated: Jul 6, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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σ0π2の電子構成を持つ安定したロジウムコーディネートカルベン

Chaopeng Hu1, Xin-Feng Wang1, Jiancheng Li1

  • 1Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, P. R. China.

Science (New York, N.Y.)
|January 4, 2024
PubMed
まとめ

独特の電子状態を持つ新しいロジウムコーディネートカルベンを発見した. この両性カルベンは,従来のカルベン化合物とは異なる異常な反応性を表している.

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This lesson delves into the geometry of a radical, which is influenced by the electronic structure of the molecule. The principle is similar to that of a lone pair, where the unpaired electron influences the geometry at the radical center.
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