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エチレン形成酵素のグロブ状の最終段階のステリック Perturbationは,3-Hydroxypropionateとプロピレンの生産を可能にします.

  • 0Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States.

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The Diels–Alder reaction is one of the robust methods for synthesizing unsaturated six-membered rings. The reaction involves a concerted cyclic movement of six π electrons: four π electrons from the diene and two π electrons from the dienophile.

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In the first...

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If a set of reactants can yield multiple constitutional isomers, but one of the isomers is obtained as the major product, the reaction is said to be regioselective. In such reactions, bond formation or breaking is favored at one reaction site over others.
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