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Updated: Jul 5, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

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アリル塩化物とアルコールのチオエーサーの光化学的有機触媒合成

Shuo Wu1, Thomas Hin-Fung Wong1, Paolo Righi2

  • 1ICIQ - Institute of Chemical Research of Catalonia, Avinguda Països Catalans 16, 43007 Tarragona, Spain.

Journal of the American Chemical Society
|January 24, 2024
PubMed
まとめ

この研究は,アリルアルキルチオエーテルを有機触媒と容易に入手可能な出所材料を用いて合成するための新しいチオールフリーメソッドを導入する. このシンプルなプロトコルは 穏やかな環境下で作動し ティオエーテル生産に よりグリーンな代替手段を 提供します

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Preparation and Reactions of Sulfides

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This lesson delves into the conversion of alcohols to corresponding alkyl halides and the mechanism of action for different reagents. Typically, the hydroxyl group is first protonated to convert it to a stable leaving group. Consequently, based on the starting alcohol, the mechanism undergoes either of the nucleophilic substitution routes, SN1 or SN2. Tertiary alkyl halides are made using the two-step SN1 mechanism that occurs via a carbocation intermediate, which is stabilized by...
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