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Updated: Jul 4, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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アンビフィリックメタロフォスフィニデンのシントンとしてルテノフォスファノルカルディエン

Tyler G Saint-Denis1, T Alexander Wheeler1, Qingchuan Chen1

  • 1Department of Chemistry, University of California, Berkeley, Berkeley, California 94720-1460, United States.

Journal of the American Chemical Society
|February 9, 2024
PubMed
まとめ

ルテニウムカルベンの複合体は,ナトリウムフォスファエチノラートと反応し,新しいフォスファノルカラディエンを形成する. この中間物質は両性反応性を示し,様々なPを含む有機金属化合物を産生する.

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Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
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Preparation and Reactions of Sulfides02:26

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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