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Updated: Jul 3, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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トリプル・ラジカル・ソートによるアルケンのダイアキル化

Johnny Z Wang1, William L Lyon1, David W C MacMillan2

  • 1Merck Center for Catalysis at Princeton University, Princeton, NJ, USA.

Nature
|February 13, 2024
PubMed
まとめ

双分子同溶性置換 (SH2) 触媒は,C3) -C3) 結合形成のための選択的基質分類を可能にします. この新しい方法は,3つの基質種を分化することでアルケンのダイアキル化を実現し,複雑な分子合成を加速します.

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