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Updated: Jul 3, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

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キラルロックされたビスペリレンダイミドマクロサイクル:キラルセルフアセンブリと円形の偏光への影響

Samuel E Penty1, Georgia R F Orton1, Dominic J Black2

  • 1School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, U.K.

Journal of the American Chemical Society
|February 14, 2024
PubMed
まとめ

研究者らは,高度な超分子材料のためのペリレンダイミド (PDIs) を使用して安定したキラルマクロサイクルを開発した. このブレークスルーにより,セルフアセンブリを正確に制御でき,新しいキラル PDI 材料で円形偏光 (CPL) が強化されます.

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Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals

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Stereoisomerism of Cyclic Compounds

In this lesson, we delve into the role of ring conformation and its stability, which determines the spatial arrangement and, consequently, the molecular symmetry and stereoisomerism of cyclic compounds. 1,2-Dimethylcyclohexane is used as a case study to evaluate the possible number of stereoisomers. Here, given the multiple (n = 2) chiral centers, there are 2n = 4 possible configurations that lack a plane of symmetry, as the ring skeleton exists in a non-planar chair conformation. In addition,...
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Selection Rules: Thermal Activation
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