関連する実験動画

Updated: Jul 1, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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エナチオセレクティブのカリウム触媒によるウィティグ・オレフィネーション

Jake Z Essman1, Eric N Jacobsen1

  • 1Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.

Journal of the American Chemical Society
|March 7, 2024
PubMed
まとめ

この研究は,カリウムイソチオurea-ボロナート触媒を用いたキラルアルケンの生成のための新しい非対称な触媒を導入しています. この方法は,Wittigのオレフィネーションで高いエンアンチオ濃度を達成し,貴重なキラル分子への新しい経路を提供します.

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