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Updated: Jul 1, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

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ステレオセレクティブ・リング・エクスパンション・メタテシス カチオンモリブデン・アルキリジン・N-ヘテロサイクル・カルベン・コンプレックスによるポリメリゼーション

Patrick Probst1, Jonas Groos1, Dongren Wang1

  • 1Institute of Polymer Chemistry, Pfaffenwaldring 55, D-70569 Stuttgart, Germany.

Journal of the American Chemical Society
|March 14, 2024
PubMed
まとめ

モリブデン触媒は,サイクルオレフィンのリング膨張メタテシスポリメリゼーション (REMP) を可能にし,サイクルポリマーを生成します. 調整された触媒は,機能的なノルボネンのポリメリゼーションにおいて高いステレオ選択性を達成する.

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