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Updated: Jun 29, 2025

Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
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不活性アルケンとダイエンの鉄触媒 [2 + 2]サイクル添加におけるリガンド場感受性スピン加速

Hanna H Cramer1, Coralie Duchemin1, Carli B Kovel1

  • 1Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.

Journal of the American Chemical Society
|March 27, 2024
PubMed
まとめ

酸化還元活性ピリジン ((ダイミン)) リガンドを持つ鉄触媒は,燃料およびリサイクル可能なポリマーの可逆 [2+2] サイクル添加を可能にします. リガンドの設計はスピン加速度に影響し,これは触媒における効率的なC−C結合形成に不可欠である.

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