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Updated: Jun 27, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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アルキル・サイクロプロピル・ケトンの触媒形式 [3 + 2] サイクル添加: SmI2の作用 触媒安定化

Jack I Mansell1, Song Yu1, Muze Li1

  • 1Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, U.K.

Journal of the American Chemical Society
|April 25, 2024
PubMed
まとめ

アルキル・サイクロプロピルケトンは現在,触媒性サイクロアディションの活性の高い基質であり,複雑なsp3豊富な分子を生成する. SmI2ベースの新しい条件は,これらの挑戦的な基板を活性化し,貴重な製品の効率的な合成を可能にします.

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