高電圧Na3V2を有効にする二重-CN群の電解質設計)
Mingqin Jiang1,2, Tianyu Li1, Yanling Qiu1
1Division of Energy Storage, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
Journal of the American Chemical Society
|April 26, 2024
まとめ
研究者は高エネルギー密度のナトリウムイオン電池に 新しい電解質添加物を開発しました この添加物は,電極に保護インターフェースを形成することで,電池の性能を改善します.
科学分野:
- 材料科学
- 電気化学
- エネルギー貯蔵
背景:
- ナトリウムイオン電池 (SIB) はエネルギー貯蔵に不可欠であり,Na3V2 ((PO4) 2F3カトドはエネルギー密度が高い.
- SIBの高電圧操作には,Na/Na+に対して最大4.2Vの電位で分解に耐える電解質が必要です.
- 高圧SIBの循環性を改善するには,安定した電極-電解質インターフェースが必要です.
研究 の 目的:
- ナトリウムイオン電池のための高圧耐性電解質添加物の設計と合成.
- ディニトリル添加物を用いてインターフェース形成のメカニズムを調査する.
- 開発された電解質でSIBの電気化学性能とサイクル安定性を評価する.
主な方法:
- ディニトリル添加物 (例えば,スッキニニトリル) を含む電解質製剤.
- サイクルボルトメトリーとガルバノスタティックサイクルを含む電気化学的特徴付け.
- インターフェースの組成を調べるための表面分析技術 (XPS,EISなど)
主要な成果:
- ディニトリル添加物は,Na3V2 ((PO4) 2F3) カトドに安定した絶縁層 (CN-/NCO-/Na3N濃縮) を形成する.
- 設計された電解質を使用したSIBは,高電圧 (2-4.3V対Na/Na+) で優れたサイクル安定性を示した.
- 具体例として,1C (1,5-ディシアノペンタン) での95. 07%の容量保持と1000サイクル後の5C (スッキニニトリル) での93. 0%の容量保持があります.
結論:
- ディニトリル添加物は,高圧ナトリウムイオン電池のための堅固な固体電解質インターフェーズを構築するのに有効です.
- 提案された電解質設計戦略は,Na3V2 ((PO4) 2F3) ベースのSIBの循環性と安定性を大幅に改善します.
- この研究は,次世代の高エネルギー密度の電解質を開発するための新しいアプローチを提供します.
関連する概念動画
Batteries and Fuel Cells
27.3K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.3K
Ion Exchange
591
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
591
Ionic Strength: Effects on Chemical Equilibria
1.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
1.5K
Electrolyte and Nonelectrolyte Solutions
62.9K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
62.9K
Electrolysis
26.3K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.3K
Voltaic/Galvanic Cells
57.1K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
57.1K


