Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Colloidal precipitates01:09

Colloidal precipitates

565
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
565
Colloids03:22

Colloids

17.4K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.4K
Hydrogen Bonds00:26

Hydrogen Bonds

121.2K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
121.2K

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Protein-Solvent Interface Controls Proton-Coupled Reactivity in Cryptochrome 4a.

Journal of the American Chemical Society·2026
Same author

Extended Lagrangian molecular dynamics on vibronic surfaces in the nuclear-electronic orbital framework.

The Journal of chemical physics·2026
Same author

General Expression for Vibronic Coupling in Proton-Coupled Energy Transfer.

Journal of chemical theory and computation·2026
Same author

Capturing nuclear quantum effects in high-pressure superconducting hydrides and ice with nuclear-electronic orbital theory.

Proceedings of the National Academy of Sciences of the United States of America·2026
Same author

Non-ideal stoichiometry and thermochemistry of aqueous iridium oxide nanoparticles in proton-coupled electron transfer and oxygen-atom transfer.

Chemical science·2026
Same author

Proton-Coupled Electron and Energy Transfer in Molecular Triads.

Accounts of chemical research·2026

関連する実験動画

Updated: Jun 26, 2025

Synthesis and Characterization of Amphiphilic Gold Nanoparticles
10:09

Synthesis and Characterization of Amphiphilic Gold Nanoparticles

Published on: July 2, 2019

17.5K

コロイド・ゴールドナノ粒子の水素

Noreen E Gentry1, Aiko Kurimoto1, Kai Cui1

  • 1Department of Chemistry, Yale University, New Haven, Connecticut 06520-8107, United States.

Journal of the American Chemical Society
|May 14, 2024
PubMed
まとめ

コロイド黄金ナノ粒子 (AuNPs) は,軽度な条件下で重要な水素を結合し,その応用に不可欠な酸化還元プロセスである. この水素結合は,ナノ粒子サイズと表面の欠陥によって制限されます.

科学分野:

  • ナノ材料科学
  • 物理化学
  • 表面科学

背景:

  • コロイド性金ナノ粒子は広く使用されているが,その酸化還元化学は完全に理解されていない.
  • 既存の研究は 陽子の関与ではなく 電子の移転に焦点を当てています

研究 の 目的:

  • 水性金ナノ粒子 (AuNPs) の基本的な酸化還元化学を調査する.
  • 温和な条件下でAuNPに結合する水素 (電子+陽子) の程度を定量化する.

主な方法:

  • 水溶液中の5 nm AuNPの酸化および還元反応の定位試験
  • 表面プラズモン共鳴 (SPR) 光学吸収を用いたモニタリング反応.
  • SPRのシフトと反応メカニズムを解釈するための計算研究.

主要な成果:

  • AuNPは,軽度な還元および酸化条件下で大量に水素 (電子+陽子) を結合する.
  • 水素結合は5nmのAuNPで約30%の表面カバーに制限され,より大きなナノ粒子はより少ないカバーを示します.
  • SPRは表面水素に対して非常に敏感であり,溶液変化と区別される.

結論:

さらに関連する動画

A Simple Method for the Size Controlled Synthesis of Stable Oligomeric Clusters of Gold Nanoparticles under Ambient Conditions
08:21

A Simple Method for the Size Controlled Synthesis of Stable Oligomeric Clusters of Gold Nanoparticles under Ambient Conditions

Published on: February 5, 2016

22.0K
Gold Nanoparticle Synthesis
13:42

Gold Nanoparticle Synthesis

Published on: July 10, 2021

14.5K

関連する実験動画

Last Updated: Jun 26, 2025

Synthesis and Characterization of Amphiphilic Gold Nanoparticles
10:09

Synthesis and Characterization of Amphiphilic Gold Nanoparticles

Published on: July 2, 2019

17.5K
A Simple Method for the Size Controlled Synthesis of Stable Oligomeric Clusters of Gold Nanoparticles under Ambient Conditions
08:21

A Simple Method for the Size Controlled Synthesis of Stable Oligomeric Clusters of Gold Nanoparticles under Ambient Conditions

Published on: February 5, 2016

22.0K
Gold Nanoparticle Synthesis
13:42

Gold Nanoparticle Synthesis

Published on: July 10, 2021

14.5K
  • 水素はAuNP表面のエッジ,コーナー,欠陥部位に結合し,ステキオメトリックの制限とサイズ効果を説明します.
  • AuNPの実質的で安定した表面水素は,環境を減少させるための触媒と生物医学に影響を及ぼします.
  • この発見は,AuNPの酸化還元化学の伝統的な電子中心的見解に異議を唱える.