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Updated: Jun 26, 2025

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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Solid-phase Synthesis of [4.4] Spirocyclic Oximes

Published on: February 6, 2019

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単離可能なスピロサイクリックシリロン:π-デロカライズされたスピロ[3.3]ヘプタシラ-2,6-ジリドン

Meldon Yi-Shuo Wee1, Shina Quek1, Chi-Shiun Wu2

  • 1School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 637371 Singapore.

Journal of the American Chemical Society
|May 16, 2024
PubMed
まとめ

最小のスパイロサイクリック・テトリロン分子を合成しました 独特の電子特性を持つ新種のシリコンを含む分子です この画期的な発見は シリコン化学と材料科学に 新たな道を開きます

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The Diels–Alder reaction is one of the robust methods for synthesizing unsaturated six-membered rings. The reaction involves a concerted cyclic movement of six π electrons: four π electrons from the diene and two π electrons from the dienophile.
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Removing one hydrogen from the intervening CH2 group...
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