結合π結合と電子トポロジカルトランジションを誘導し,水素進化の触媒を強化する

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Updated: Jun 25, 2025

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

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Tan Zhang1, Zhen Jiang1, Andrew M Rappe1

  • 1Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, United States.

Journal of the American Chemical Society
|May 22, 2024
PubMed
まとめ

トポロジカルな材料は水素進化の電気触媒を強化する. 金属フタロシアニンベースの共性有機フレームワークのトポロジカル・ギャップレス・バンドは,エネルギーバリアを大幅に削減し,効率を改善します.

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Reduction of Alkenes: Catalytic Hydrogenation

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Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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