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Updated: Jun 24, 2025

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
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Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

Published on: July 26, 2018

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ジルコナジリジン媒介のNi-カタライズされたダイアステロセレクティブC ((sp2) -グリコシレーション

Yu Gan1, Jun-Feng Zhou1, Xuejiao Li1

  • 1School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.

Journal of the American Chemical Society
|June 11, 2024
PubMed
まとめ

この研究は,ステレオ選択C-グリコシド結合形成のための新しいジルコナジリジン媒介ニッケル触媒を導入する. この方法は,還元性触媒におけるキラルバイオクサゾリン (biOx) リガンドを使用して,アノメリック構成を正確に制御します.

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