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Updated: Jun 23, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
12:19

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

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ヴィニルサイクロプロパンとメタルラジカルによるダイナミックステレオ変異

Marvin Mendel1, Teresa M Karl1, Jegor Hamm1

  • 1Institute of Organic Chemistry, RWTH Aachen University, Aachen, Germany.

Nature
|June 19, 2024
PubMed
まとめ

ニッケル ((I) メタロラジカル触媒は,ヴィニルサイクロプロパンの可逆性シス/トランスイソメリゼーションを可能にし,従来の急激反応に持続可能な代替手段を提供している. この新しいアプローチは,複雑な分子合成のための穏やかな条件と高いステレオ化学制御を達成します.

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