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Nuclear Fusion02:45

Nuclear Fusion

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The process of converting very light nuclei into heavier nuclei is also accompanied by the conversion of mass into large amounts of energy, a process called fusion. The principal source of energy in the sun is a net fusion reaction in which four hydrogen nuclei fuse and ultimately produce one helium nucleus and two positrons.
A helium nucleus has a mass that is 0.7% less than that of four hydrogen nuclei; this lost mass is converted into energy during the fusion. This reaction produces about...
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Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

34.7K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
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Nuclear Transmutation03:20

Nuclear Transmutation

17.5K
Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed...
17.5K
Exceptions to the Octet Rule02:55

Exceptions to the Octet Rule

28.1K
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
28.1K
Molecular Orbital Theory II03:51

Molecular Orbital Theory II

19.1K
Molecular Orbital Energy Diagrams
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Noble Gases02:54

Noble Gases

17.4K

The elements in group 18 are noble gases (helium, neon, argon, krypton, xenon, and radon). They earned the name “noble” because they were assumed to be nonreactive since they have filled valence shells. In 1962, Dr. Neil Bartlett at the University of British Columbia proved this assumption to be false.
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Updated: Jun 23, 2025

Synthesis and Characterization of Supramolecular Colloids
09:26

Synthesis and Characterization of Supramolecular Colloids

Published on: April 22, 2016

9.8K

N2型超原子分子合成

Ryohei Saito1,2, Katsuhiro Isozaki1,2, Yoshiyuki Mizuhata1

  • 1Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.

Journal of the American Chemical Society
|June 20, 2024
PubMed
まとめ

研究者は2つの超原子,M2Au17 (M = Pd,Pt) の間の三重結合を持つ新しい超原子分子を合成しました. この発見は 超原子結合と電子の性質の理解に 新たな道を開きます

科学分野:

  • * 無機化学
  • * ナノ材料科学
  • * 超分子化学

背景:

  • * 超原子間の複数の結合の探索は新興分野です.
  • * 超原子分子は従来の分子とは異なるユニークな性質を持っています.
  • * 新しい超原子構造の形成と特性を理解することは極めて重要です.

研究 の 目的:

  • * 三重結合を持つ窒素 (N2) 型超原子分子を合成し,特徴づけること.
  • * これらの新しい超原子構造の形成機構を調査する.
  • * 合成された超原子分子の電子構造と性質を明らかにする.

主な方法:

  • *MAu12超原子の光誘発融合によりM2Au17ナノクラスター (M = Pd, Pt) が形成される.
  • * [AuPR3]+種の連続的な電子移転と分離によって達成された合成.
  • * 固体構造のX線結晶学と電子構造の密度関数理論 (DFT) の計算を用いた特徴付け

主要な成果:

  • 超原子三重結合を備えたM2Au17ナノクラスタの合成と構造確認が成功しました.
  • * DFTの計算により,超原子の詳細な電子構造が明らかになった.
  • * 電子吸収特性の分析は,超原子分子軌道間の対称性依存の電子移行を示した.

さらに関連する動画

Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
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Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride

Published on: July 8, 2021

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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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関連する実験動画

Last Updated: Jun 23, 2025

Synthesis and Characterization of Supramolecular Colloids
09:26

Synthesis and Characterization of Supramolecular Colloids

Published on: April 22, 2016

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Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
04:51

Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride

Published on: July 8, 2021

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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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結論:

  • * この研究は,超原子間の三重結合の形成の可能性を示しています.
  • * この 超原子 三重結合 の 電子 の 振る舞い は,従来 の 分子 の 振る舞い を 模倣 し て い ます.
  • * この研究は,超原子系における結合の理解を拡大し,新しい材料の可能性を開きます.