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Updated: Jun 23, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Published on: November 9, 2019

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双機能有機ケージにおける酵素のようなアシル転移触媒

Keith G Andrews1,2, Tomasz K Piskorz1, Peter N Horton3

  • 1Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Oxford OX1 3TA, U.K.

Journal of the American Chemical Society
|June 24, 2024
PubMed
まとめ

堅固なヘクサアミドケージは,酵素活性部位を模倣して,アシル移転反応を触媒化する. ピリジンとカーボキシル酸のグループを持つ二機能ケージは,内部触媒による効率的なエステル化を可能にし,10^4の速度加速を達成します.

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