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Updated: Jun 23, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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サイクロヘクセンからメタテシス活性タングステンアルキリデン複合体の熱形成

Milan Maji1, Adenilson Sousa-Silva2, Xavier Solans-Monfort2

  • 1Department of Chemistry, University of California at Riverside, Riverside, California 92521, United States.

Journal of the American Chemical Society
|June 25, 2024
PubMed
まとめ

トングステンの複合体は,リング収縮反応を経て,新しい循環構造と転移活性アルキリデンを形成する. これらの発見は,オレフィン転移の重要なステップであるtungstacyclopentanesの熱環収縮を確認します.

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