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Updated: Jun 22, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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D4-対称ディロジウムテトラキス (ビナフチルフォスファート) 非活性化C-H結合のエナチオセレクティブ機能化のための触媒

Ziyi Chen1, Kristin Shimabukuro1, John Bacsa1

  • 1Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States.

Journal of the American Chemical Society
|July 3, 2024
PubMed
まとめ

新しいディロジウム触媒は,高度にエナチオセレクティブなC-H機能化を可能にします. 改変されたビナフチルフォスファートリガンドは最適なD4対称性を達成し,低触媒負荷でサイト選択反応のための以前の触媒を上回ります.

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