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非対称 Cu-N2 シングル・アトム・サイトに対する圧力依存CO2の電子還元

Haoyang Wu1, Benqiang Tian1, Wenhai Xu1

  • 1State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, P. R. China.

Journal of the American Chemical Society
|July 12, 2024
PubMed
まとめ

単原子触媒の圧力調節戦略を開発し,二酸化炭素をメタンに変換する高効率を達成しました. この方法は選択性を高め,望ましくない反応を抑制し,触媒の性能を向上させます.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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