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Updated: Jun 20, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

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M/P ヘリシティー・スイッチングとキラル・アンプリフィケーション

Kotaro Matsumura1, Keigo Kinjo1, Kotaro Tateno1

  • 1Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.

Journal of the American Chemical Society
|July 19, 2024
PubMed
まとめ

新しいメタロフォルドファイマーには,溶媒刺激に反応する切り替え可能な螺旋性がある. この発見は反応性のあるキラル材料の開発と 分子認識プロセスを理解するための新しい道を開きます

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Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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