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Updated: Jun 19, 2025

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
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Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine

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制御されたカーギル再配列によって有効化された (-) -クリニペリンAとBの簡潔な総合成

Bo Xu1, Ziyao Zhang1, Dean J Tantillo2

  • 1Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.

Journal of the American Chemical Society
|July 25, 2024
PubMed
まとめ

複合的なテトラキナンの骨格を特徴とする ディターペンの天然産物 (-) - クリニペリンAとBを合成しました 主なステップは,コジコフスキー β-アルキル化,光化学 [2 + 2] サイクル添加,およびカーギル再配列でした.

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