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Updated: Jun 18, 2025

Ion-Exchange Membranes for the Fabrication of Reverse Electrodialysis Device
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Ion-Exchange Membranes for the Fabrication of Reverse Electrodialysis Device

Published on: July 20, 2021

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アニオン交換膜水電解剤におけるイオノマー酸化による劣化副産物をOperando Ramanスペクトロスコーピーは明らかにする

Derrick S Maxwell1, Ian Kendrick2, Sanjeev Mukerjee1

  • 1Northeastern University, 360 Huntington Avenue, Boston, Massachusetts 02115, United States.

Journal of the American Chemical Society
|July 30, 2024
PubMed
まとめ

研究者らは,非プラチナグループ金属 (PGMフリー) アニオン交換膜水電解剤 (AEMWE) で分解メカニズムを発見した. オペランド・ラーマン光学により,酸化条件下でポリマー骨幹鎖の分裂を引き起こすフリーラジカル経路が明らかになった.

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Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
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