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Updated: Jun 17, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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炭素中心の基質による有機銅の酸化置換

Yuecheng Weng1, Yuxuan Jin1, Jian Wu2

  • 1State Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China.

Journal of the American Chemical Society
|August 8, 2024
PubMed
まとめ

この研究は,銅による触媒反応の新たなメカニズムを明らかにした. フッ素アルキル銅 (III) 複合体は,トリフローロメチル化のための"酸化置換"経路を示唆する,ラジカルと銅 (II) 種を生成する.

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Radicals can be formed by adding a radical to a spin-paired molecule. This is typically observed with unsaturated species, where the addition of a radical across the π bond leads to the production of a new radical by dissolving the π bond. For example, the addition of a Br radical to an alkene yields a carbon-centered radical.
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