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Updated: Jun 15, 2025

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones

Published on: February 7, 2019

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シクロプロピル基のシリコンアナログは,Si-Br結合を特徴とする非常に安定したサイクリックディジレン化合物から派生する

Ryoma Ohno1, Kei Ota1, Nagisa Nishimura1

  • 1Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Osaka 577-8502, Japan.

Journal of the American Chemical Society
|August 27, 2024
PubMed
まとめ

研究者らは安定したブロモサイクロトリシレン化合物Si3Br(Eind) 3を合成し,独特の反応性を示した. さらに減少すると,C-H結合の活性化によって熱的に安定したサイクロトリシアニルラジカルが生み出され,新しいシリコン環構造が明らかになる.

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