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Updated: Jun 14, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Published on: March 24, 2018

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CeF62-とCeCl62における軌道エネルギー,軌道重複,および結合共相性との反直感的な関係

Jacob A Branson1,2, Patrick W Smith2, Dumitru-Claudiu Sergentu3,4

  • 1Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States.

Journal of the American Chemical Society
|September 6, 2024
PubMed
まとめ

セリウム化合物 (Ce) の共性混合は,CeF62-のCeCl62-よりも少ない. これは,軌道が重なり合うだけでなく,f要素系における結合に影響を与えるエネルギーギャップによるものです.

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