JoVE - Journal of Visualized Experiments
JoVE Visualize
Contact Us
このページは機械翻訳されています。他のページは英語で表示される場合があります。 View in English

耐久性のあるワッカー型酸化に向けて,ゼオライトで囲まれた孤立したパラジウムリドックスセンター

  • 0Key Laboratory of Advanced Energy Materials Chemistry of Ministry of Education, College of Chemistry, Nankai University, Tianjin 300071, P. R. China.
Journal of the American Chemical Society +

|

2024年9月26日

PubMedで要約を見る

まとめ

この要約は機械生成です。

関連する概念動画

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide 02:44

9.9K

Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.

Syn Dihydroxylation Mechanism
The reaction comprises a two-step mechanism. It begins with the addition of osmium tetroxide across the alkene double bond in a concerted manner forming a...

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate 02:21

11.1K

Alkenes can be dihydroxylated using potassium permanganate.  The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.

The mechanism begins with the syn addition of a permanganate ion (MnO4−) across the same side of the alkene π bond, forming a cyclic manganate ester intermediate. Next, the hydrolysis of the cyclic ester with water gives a cis-diol...

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation 02:17

3.2K

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...

Oxidative Cleavage of Alkenes: Ozonolysis 01:46

10.0K

In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.

Ozonolysis proceeds through an oxidative cleavage reaction. The first step is the electrophilic addition of ozone across the alkene double bond, forming an unstable molozonide intermediate, which reacts further to form a carbonyl and a carbonyl oxide. These intermediates...

Oxidation-Reduction Reactions 03:11

64.5K

Oxidation–Reduction Reactions

Earth’s atmosphere contains about 20% molecular oxygen, O2, a chemically reactive gas that plays an essential role in the metabolism of aerobic organisms and in many environmental processes that shape the world. The term oxidation was originally used to describe chemical reactions involving O2, but its meaning has evolved to refer to a broad and important reaction class known as oxidation–reduction (redox) reactions. 

Some redox reactions...

Redox Equilibria: Overview 01:23

543

A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...