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Updated: Jun 12, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

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安定したストレインドナーフリーシラノンおよびそのNHCで安定したディシラサイクロブタディエンおよびサイクルアルケニルシリレン

Yazhou Ding1, Wen Jin1, Chen-Huan Liu1

  • 1State Key Laboratory of Elemento-Organic Chemistry and Frontiers Science Center of New Organic Matter, Nankai University, Tianjin 300071, People's Republic of China.

Journal of the American Chemical Society
|September 26, 2024
PubMed
まとめ

研究者らは一酸化窒素を用いて安定したシラノーン (シリコン-酸素の二重結合化合物) を合成した. このシラノンは驚くべき熱安定性を示し,有機シリコン化学における新しい経路を提供するユニークな反応を経験します.

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Introduction
A comparison of the enthalpies of hydrogenation of dienes reveals that conjugated dienes release less heat on hydrogenation, rendering them more stable than their nonconjugated analogs.
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Characteristics of the diene
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