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Updated: Jun 15, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

ケトンと非活性化アルキル電ophilesの触媒非対称なバービア反応

Hanyu Xia1, Xingni Jiang1, Di Lin1

  • 1Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, 130 Meilong Road, Shanghai 200237, China.

Journal of the American Chemical Society
|October 3, 2024
PubMed
まとめ

この研究は,ケトンとアルキルハリドから複雑なキラル三次アルコールを生成するための新しいコバルト触媒型反応を導入しています. この効率的な方法は,薬剤ソフドラを含む,挑戦的なテトラ置換型ステレオセンターの合成を可能にします.

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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

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