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関連する概念動画

Atomic Nuclei: Nuclear Spin State Population Distribution01:14

Atomic Nuclei: Nuclear Spin State Population Distribution

956
Near absolute zero temperatures, in the presence of a magnetic field, the majority of nuclei prefer the lower energy spin-up state to the higher energy spin-down state. As temperatures increase, the energy from thermal collisions distributes the spins more equally between the two states. The Boltzmann distribution equation gives the ratio of the number of spins predicted in the spin −½ (N−) and spin +½ (N+) states.
956
Properties of Transition Metals02:58

Properties of Transition Metals

25.2K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
25.2K
Metallic Solids02:37

Metallic Solids

18.3K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.3K
P-N junction01:11

P-N junction

471
A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
471
Noble Gases02:54

Noble Gases

17.3K

The elements in group 18 are noble gases (helium, neon, argon, krypton, xenon, and radon). They earned the name “noble” because they were assumed to be nonreactive since they have filled valence shells. In 1962, Dr. Neil Bartlett at the University of British Columbia proved this assumption to be false.
17.3K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.0K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.0K

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関連する実験動画

Updated: Jun 10, 2025

Probe Type II Band Alignment in One-Dimensional Van Der Waals Heterostructures Using First-Principles Calculations
13:56

Probe Type II Band Alignment in One-Dimensional Van Der Waals Heterostructures Using First-Principles Calculations

Published on: October 12, 2019

7.6K

NaNiO2における移位的なヤーン=テラー変換

Liam A V Nagle-Cocco1, Annalena R Genreith-Schriever2, James M A Steele1,2

  • 1Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, United Kingdom.

Journal of the American Chemical Society
|October 14, 2024
PubMed
まとめ

この研究は,NaNiO2が排位的なヤーン・テラー変換を 経験していることを示しています. ローカル・プローブ・テクニックは,この構造変化の直接的な証拠を,ヤーン-テラー移行温度で提供します.

さらに関連する動画

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
06:44

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing

Published on: June 9, 2023

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Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
09:02

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance

Published on: April 27, 2018

7.8K

関連する実験動画

Last Updated: Jun 10, 2025

Probe Type II Band Alignment in One-Dimensional Van Der Waals Heterostructures Using First-Principles Calculations
13:56

Probe Type II Band Alignment in One-Dimensional Van Der Waals Heterostructures Using First-Principles Calculations

Published on: October 12, 2019

7.6K
Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
06:44

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing

Published on: June 9, 2023

3.1K
Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
09:02

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance

Published on: April 27, 2018

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科学分野:

  • 固体化学
  • 材料科学
  • クリスタルグラフィー

背景:

  • NaNiO2は,そのヤーン-テラー移行温度 (TJT) 以下のモノクリニック層構造を示している.
  • TJT上では,協力的なJahn-Teller歪みを失い,単位細胞の容量が増加します.

研究 の 目的:

  • NaNiO2におけるヤーン=テラー変換の性質を調査する.
  • 地元の探査技術を使って 移行メカニズムの直接的な証拠を提供する.

主な方法:

  • ニュートロン総分散
  • 固体核磁共振 (NMR)
  • 拡張X線吸収細部構造 (EXAFS)
  • アブ・イニシオ分子動力学 (AIMD) シミュレーション

主要な成果:

  • 地元の探査実験は 移位性Jahn-Teller移行の直接的な証拠を提供します
  • AIMDのシミュレーションは,移行の移転性を支持しています.
  • この研究は,直接的なローカルプローブ観測を用いた 移位的なヤーン=テラー移行を初めて実証したものである.

結論:

  • NaNiO2のJahn-Tellerの移行は,位移していることが確認されています.
  • ローカル・プローブ・テクニックは,移位相移行のメカニズムを特徴づけるのに有効である.