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Updated: Jun 10, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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NHC/CAACベースのカルボディカルベンのクロスカップリング:電子欠乏ディラジカロイドの合成

Vasu Malhotra1, Benedict J Elvers2, Ramapada Dolai1

  • 1Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad 500046, India.

Journal of the American Chemical Society
|October 19, 2024
PubMed
まとめ

ニッケル ((0)) -触媒化されたクロスカップリング反応は,カルボディカルベンとアリルハリドから新しいダイラジカロイドの合成を可能にします. このモジュール式アプローチにより,電子特性を調節し,ラジカル-ラジカル二重化経路を探索することができます.

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