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Ion Exchange01:17

Ion Exchange

559
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
559
Batteries and Fuel Cells03:12

Batteries and Fuel Cells

27.1K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.1K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.3K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Alkyl Halides02:45

Alkyl Halides

16.3K
Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
16.3K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.5K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.5K
Ions as Acids and Bases02:54

Ions as Acids and Bases

23.6K
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
23.6K

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Updated: Jun 9, 2025

Extending the Lifespan of Soluble Lead Flow Batteries with a Sodium Acetate Additive
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Extending the Lifespan of Soluble Lead Flow Batteries with a Sodium Acetate Additive

Published on: January 7, 2019

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水性ハリド流電池のための柔らかい硬いズウィテリオン添加物

Gyohun Choi1, Patrick Sullivan1, Xiu-Liang Lv1

  • 1Department of Materials Science and Engineering, University of Wisconsin-Madison, Madison, WI, USA.

Nature
|October 24, 2024
PubMed
まとめ

ソフト・ハード・ズウィテリオン・トラッパー (SH-ZIT) は,ポリハリドの発生を防ぐことで,安定した高容量水性酸化還元流電池を可能にします. この突破は1000回以上の高電荷状態で 効率的なグリッドエネルギー貯蔵を可能にします

さらに関連する動画

A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery
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A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

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関連する実験動画

Last Updated: Jun 9, 2025

Extending the Lifespan of Soluble Lead Flow Batteries with a Sodium Acetate Additive
08:35

Extending the Lifespan of Soluble Lead Flow Batteries with a Sodium Acetate Additive

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A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

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科学分野:

  • 材料科学
  • 電気化学
  • 持続可能なエネルギー

背景:

  • 水性酸化還元流電池 (RFB) は,グリッドのエネルギー貯蔵に有望である.
  • ハリド基のカトライトは,ポリハリド形成により,相分離,電荷状態の低下 (SoC),およびデバイスの故障につながる課題に直面しています.

研究 の 目的:

  • 水性RFBにおける均質ハライド循環のための新しい複合剤を開発する.
  • ポリハリド形成の限界を克服し,バッテリーの性能と長寿を改善します.

主な方法:

  • ポリハリド複合剤としてのソフトハードズウィテリオントラッパー (SH-ZIT) の設計と特徴付け.
  • ハリドカソライトを使ったSH-ZITを使用したフローバッテリーの電気化学サイクル.
  • 様々な電荷状態と濃度でのポリハリドの行動の調査.

主要な成果:

  • SH-ZITは効果的に複合ポリハリドを合成し,均質な水循環を可能にします.
  • フロー電池は1000サイクル以上で,衰えることなく40mA/cm2で99.9%以上のクーロンビック効率を示した.
  • 高温で安定した動作と,ブロミドカソライトの90%までの均質なサイクルが達成されました.
  • 80% SoCで超高カトライト容量利用率 (>120 Ah/L) と亜鉛アノドとの互換性が実証された.

結論:

  • SH-ZITは,高性能水性RFBのハライドカトライトを安定させるのに有効です.
  • この技術はエネルギー貯蔵容量とサイクル寿命を大幅に高めます
  • SH-ZITは,エネルギー貯蔵アプリケーションにおける高度なポリハリドシステムの探索のための新しい道を開きます.