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Updated: Jun 8, 2025

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
08:46

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI

Published on: November 22, 2016

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トライアリルフォスフィン・ラジカル・カチオンを隔離し,空間間でのラジカル・デロカライゼーションによって電子的に安定させる

Gyeongho Ham1, Younghun Kim1, Woo-Dong Jang1

  • 1Department of Chemistry, Yonsei University, Seoul 03722, Republic of Korea.

Journal of the American Chemical Society
|November 7, 2024
PubMed
まとめ

この研究では,ステリック・バルクではなく,電子効果によって安定した新しいトリアリルフォスフィン・ラジカル・カチオンについて説明しています. この電子の安定化により 独特の4中心の7電子の結合が可能になり 激素のカチオン化学を進めるのです

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