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Updated: Jun 7, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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Pd2L4コーディネーションケージにおける溶媒誘導社会キラル自己分類

Alexandre Walther1, Gers Tusha2, Björn Schmidt1

  • 1Department of Chemistry and Chemical Biology, TU Dortmund University, Otto Hahn Str. 6, 44227 Dortmund, Germany.

Journal of the American Chemical Society
|November 17, 2024
PubMed
まとめ

チラルのリガンドはPd2L4ケージを形成する. 溶媒分子は,より短いリガンドで自己分類を駆動し,水素結合によって単一のメソトランスケージ同位体を生成する. より長いリガンドは自己分類ではなく,金属複合体を結合し,エナンティオマーを区別するケージを形成する.

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