Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Catalysis02:50

Catalysis

26.7K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
26.7K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

3.2K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.2K
Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

11.8K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
11.8K
Catalytically Perfect Enzymes01:07

Catalytically Perfect Enzymes

3.9K
The theory of catalytically perfect enzymes was first proposed by W.J. Albery and J. R. Knowles in 1976. These enzymes catalyze biochemical reactions at high-speed. Their catalytic efficiency values range from 108-109 M-1s-1. These enzymes are also called 'diffusion-controlled' as the only rate-limiting step in the catalysis is that of the substrate diffusion into the active site. Examples include triose phosphate isomerase, fumarase, and superoxide dismutase.
 
Most enzymes...
3.9K
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation01:28

Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation

4.3K
Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
4.3K
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

7.6K
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
7.6K

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Bifurcation of *COOH Pathway Determines HCOOH Formation in CO<sub>2</sub> Electroreduction on Bismuth.

Angewandte Chemie (International ed. in English)·2026
Same author

Magnetocrystalline Anisotropic Platinum-Palladium-Iron Ternary Intermetallic Alloy for Enhanced Fuel Cell Electrocatalysis.

Advanced materials (Deerfield Beach, Fla.)·2025
Same author

Dual-Ionic Weakly Solvating Electrolyte Design Enables Efficient Fast-Cycling of High-Voltage Anion Shuttle Batteries.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)·2025
Same author

Enhanced Cuproptosis via Metabolic Reprogramming Using Copper-Delivering Co-N-C Single-Atom Nanozyme.

ACS nano·2025
Same author

Enhanced Fe<sup>IV</sup>═O Generation via Peroxymonosulfate Activation by an Edge-Site Engineered Single-Atom Iron Catalyst.

Small (Weinheim an der Bergstrasse, Germany)·2025
Same author

Atomic-level Ru-Ir mixing in rutile-type (RuIr)O<sub>2</sub> for efficient and durable oxygen evolution catalysis.

Nature communications·2025

関連する実験動画

Updated: Jun 6, 2025

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
10:19

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation

Published on: July 18, 2017

11.9K

ヘテロゲネスな触媒のための生成式予備型変圧器

Dong Hyeon Mok1, Seoin Back1

  • 1Department of Chemical and Biomolecular Engineering, Institute of Emergent Materials, Sogang University, Seoul 04107, Republic of Korea.

Journal of the American Chemical Society
|November 22, 2024
PubMed
まとめ

CatGPTという トランスフォーマーベースの 言語モデルを開発し 新しい無機触媒構造を作り出しました このAIツールは 酸素還元反応のような 特定の用途のための 多様で正確な材料設計を作成することで 触媒の発見を加速します

科学分野:

  • 化学について
  • 材料科学
  • 人工知能

背景:

  • 新しい材料の発見は 化学と材料科学にとって 極めて重要です
  • 試行錯誤や機械学習のような 伝統的な方法が 材料設計に使われています
  • トランスフォーマーベースの言語モデルは,新しい物質構造を生成するための希望を示しています.

研究 の 目的:

  • 無機触媒の発見のための触媒生成型予備型変圧器 (CatGPT) を導入する.
  • CatGPTの有効で正確な触媒構造を生成する能力を実証する.
  • テキストコンディショニングと微調整を通じて特定の触媒タイプを生成するためのCatGPTの柔軟性を示します.

主な方法:

  • 変圧器ベースの言語モデル (CatGPT) を,無機触媒構造の大きなデータセットで訓練した.
  • 触媒生成を導くためにテキストコンディショニングと微調整を使用した.
  • 酸素還元反応 (ORR) のスクリーニングのためのバイナリ合金触媒のデータセットに微調整を適用した.

主要な成果:

  • CatGPTは有効で正確な無機触媒構造を生成します
  • このモデルは,材料の化学的空間を拡大する上で高いパフォーマンスを示しています.

さらに関連する動画

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
08:40

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

3.5K
HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin
11:15

HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin

Published on: July 23, 2016

10.2K

関連する実験動画

Last Updated: Jun 6, 2025

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
10:19

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation

Published on: July 18, 2017

11.9K
Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
08:40

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

3.5K
HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin
11:15

HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin

Published on: July 23, 2016

10.2K
  • 微調整により,2電子酸素還元反応 (2e-ORR) に特化した触媒が生成された.
  • 結論:

    • CatGPTのような生成言語モデルは 触媒の発見を加速する強力なツールです
    • CatGPTは様々な触媒構造を調査するための基礎モデルを提供します.
    • このアプローチは,望ましい性質を持つ新しい材料を発見するための大きな可能性を秘めています.