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Updated: Jun 5, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Published on: April 19, 2019

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エナチオセレクティブ・ラジカル・トリコンポーネント・ディカルボ機能化のための調節可能なチアゾリウムカルベン

Sripati Jana1, Nicolai Cramer1

  • 1Laboratory of Asymmetric Catalysis and Synthesis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|December 10, 2024
PubMed
まとめ

チラルのN-ヘテロサイクリックカルベン (NHC) 触媒は,新しい非対称な根性反応を可能にします. この研究では,エナチオセレクティブのアチル-二酸化アルキル化のために調節可能なキラルチアゾリウムカルベンを導入し,多様なキラルケトンを生成します.

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