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Updated: May 5, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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[4 + 2]サイクル添加によるアルコキシ誘導ダイアミン触媒:ベンゾ[3]-レッダーアノールのエナチオセレクティブ合成

Sayan Ray1, Deepak Behera1, Mahesh Singh Harariya1

  • 1Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India.

Journal of the American Chemical Society
|January 11, 2025
PubMed
まとめ

アルコキシ誘導のダイアミン触媒は,エナチオ選択的合成における地域選択性の制限を克服する. この新しい方法は,効率的なde novoアレン製造と新しい膜活性化合物の合成を可能にします.

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The reaction between two different carbonyl compounds comprising α hydrogen in the presence of a strong base like lithium diisopropylamide (LDA) to form a crossed aldol product is known as a directed aldol reaction. The directed aldol reaction is depicted in Figure 1.
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