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Updated: May 28, 2025

The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
12:43

The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique

Published on: November 28, 2016

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隣接するスタニリジンとフェリオスタニレン単位を持つ鉄-亜鉛複合体の合成と反応性

Yang Liu1, Franz F Westermair2, Isabelle Becker3

  • 1Institute of Inorganic Chemistry, University of Regensburg, Regensburg 93040, Germany.

Journal of the American Chemical Society
|February 11, 2025
PubMed
まとめ

新型鉄亜鉛化合物 [Fe(SnAr') 2のような重過渡金属カルビーン複合体は,小分子活性化に有望である. この研究は,その合成と多様な反応を詳細に説明し,協力的な小分子活性化におけるその可能性を強調しています.

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Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Isomerism in Complexes
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Radical Reactivity: Concentration Effects

In a radical reaction, the concentration of starting materials governs the selectivity of a radical. For example, the reaction between an alkyl halide and an alkene, in the presence of tin hydride and AIBN, begins with the generation of a tin radical. The generated radical then abstracts halogen from the alkyl halide, producing an alkyl radical. This alkyl radical can either react with tin hydride, yielding an alkane, or add to an alkene, generating a nitrile-stabilized radical, eventually...
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