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Updated: May 27, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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メタラフォトレドックス触媒によって可能となるエナチオセレクティブアルキル-アチルラジカルクロスカップリング

Tao Li1, Zhen Xu1, Yongliang Huang1

  • 1State Key Laboratory of Physical Chemistry of Solid Surfaces, Key Laboratory of Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

Journal of the American Chemical Society
|February 19, 2025
PubMed
まとめ

この研究は,高度にエナチオセレクティブな根幹対根幹交互結合 (RCC) 反応のための新しいメタラフォトレドックス法を導入する. このアプローチにより,α-アミノケトンなどの複雑なキラル分子の効率的な合成が可能になり,非対称な触媒を推進します.

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