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Updated: May 26, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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二酸化窒素還元によるトリウム窒素複合体の合成と触媒作用

Weiming Sheng1, Thayalan Rajeshkumar2, Qianyi Zhao3

  • 1State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.

Journal of the American Chemical Society
|February 24, 2025
PubMed
まとめ

研究者らは,窒素-窒素結合を二酸化窒素 (N2) で割ることによって,トリウムニトリド複合体を分離した. このアクチニド触媒は,N2をシリアミンに効率的に変換し,窒素固定化学を進める.

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Nitriles are reduced to amines in the presence of strong reducing agents like lithium aluminum hydride through a typical nucleophilic acyl substitution. The reaction requires two equivalents of the reducing agent. The reducing agent acts as a source of hydride ions.
As shown below, the mechanism involves three steps. Firstly, the hydride ion acting as a nucleophile attacks the nitrile carbon to form an anion. In the second step, a second equivalent of the hydride ion attacks the anion to...
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