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Updated: May 25, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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モノデンテート σ-受容性ボロン基リガンドベアリング正方形平面 Ni0センター

Yutaka Mondori1, Yasuhiro Yamauchi1, Takahiro Kawakita1

  • 1Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.

Journal of the American Chemical Society
|February 28, 2025
PubMed
まとめ

研究者は,ボロンベースのZ型リガンドを使用して,新しい正方形平面ニッケル ((0) コンプレクスを合成した. このブレークスルーにより,単歯型Z型リガンドを持つ安定した低価変異金属種が生まれ,従来の協調化学理論に異議を唱える.

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