Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Synthesis and Decomposition Reactions02:17

Synthesis and Decomposition Reactions

32.1K
Synthesis and decomposition are two types of redox reactions. Synthesis means to make something, whereas decomposition means to break something. The reactions are accompanied by chemical and energy changes. 
32.1K
Electrolysis03:00

Electrolysis

25.9K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
25.9K
Oxidation and Reduction of Organic Molecules01:19

Oxidation and Reduction of Organic Molecules

6.1K
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
6.1K
Radical Oxidation of Allylic and Benzylic Alcohols01:21

Radical Oxidation of Allylic and Benzylic Alcohols

1.9K
Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
1.9K
Redox Equilibria: Overview01:23

Redox Equilibria: Overview

501
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
501
Electrodeposition01:08

Electrodeposition

560
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
560

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

A polymer that reinforces luminal barrier function and attenuates inflammation in murine colitis.

Research square·2026
Same author

Addition and Correction to "Thermo-Transitioning Core-Shell Microgels Combine Cohesive Reinforcement and Noncohesive Reconfigurability to Enable 3D Bioprinting and Stabilize Tissues During Incubation<i>"</i>.

ACS biomaterials science & engineering·2026
Same author

Reversible Addition-Fragmentation Chain-Transfer Aqueous Emulsion Polymerization Observed by Transmission Electron Microscopy.

Journal of the American Chemical Society·2026
Same author

Thermo-Transitioning Core-Shell Microgels Combine Cohesive Reinforcement and Noncohesive Reconfigurability to Enable 3D Bioprinting and Stabilize Tissues During Incubation.

ACS biomaterials science & engineering·2026
Same author

Surface-Functionalized, Two-Dimensional Polymer Electrochromic Layers as Ultrafast, Multi-State Infrared Optical Gates.

Journal of the American Chemical Society·2026
Same author

Photocatalytic surface grafting of hydrophobic shells onto hydrogels.

Chemical communications (Cambridge, England)·2026
Same journal

Linker Engineering toward NIR-II Metal-Organic Framework with Maximal Emission beyond 1000 nm for Inflammatory Bowel Disease Imaging.

Journal of the American Chemical Society·2026
Same journal

Observing Kinetic Selectivity in Anthracene Photodimerization through Selective Quenching by Excited States of Proximate Rare Earth Cations.

Journal of the American Chemical Society·2026
Same journal

Sequence-Dependent Folding of Recognition-Encoded Melamine Oligomers.

Journal of the American Chemical Society·2026
Same journal

Large Thermo- and Mechanosalient Actuation via Cooperative Twist Elasticity-Induced Packing Motif Conversion.

Journal of the American Chemical Society·2026
Same journal

Discovery and Biosynthesis of Lanthipeptides Featuring an Azepinoindole Scaffold by Radical <i>S</i>-Adenosylmethionine Enzyme-Catalyzed C-C Bond Formation.

Journal of the American Chemical Society·2026
Same journal

Enantiopurity-Controlled Magnetism in a Two-Dimensional Organic-Inorganic Material.

Journal of the American Chemical Society·2026
関連記事をすべて見る

関連する実験動画

Updated: May 24, 2025

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
09:17

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes

Published on: January 30, 2015

11.8K

配列機能化と分解のためのレドックス選択性マクロ分子電解

Graham C Gilchrist1, Rhys W Hughes1, Sean R Gitter1

  • 1George & Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science & Engineering, Department of Chemistry, University of Florida, Gainesville, Florida 32611, United States.

Journal of the American Chemical Society
|March 3, 2025
PubMed
まとめ
この要約は機械生成です。

選択的マクロ分子電解は,ポリマーの改変と分解を正確に制御することができます. この電気化学的方法により,調節可能な材料の性質と複雑なポリマー構造の作成が可能になります.

さらに関連する動画

Light-driven Enzymatic Decarboxylation
09:58

Light-driven Enzymatic Decarboxylation

Published on: May 22, 2016

10.6K
Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations
13:09

Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations

Published on: January 4, 2018

39.0K

関連する実験動画

Last Updated: May 24, 2025

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
09:17

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes

Published on: January 30, 2015

11.8K
Light-driven Enzymatic Decarboxylation
09:58

Light-driven Enzymatic Decarboxylation

Published on: May 22, 2016

10.6K
Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations
13:09

Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations

Published on: January 4, 2018

39.0K

科学分野:

  • ポリマー化学
  • 電気化学
  • 材料科学

背景:

  • マクロモレキュアの改変はしばしば精密な制御がなく,材料の特性調整を制限する.
  • ポリマーの機能化と分解のための選択的方法の開発は,先進的な材料にとって極めて重要です.

研究 の 目的:

  • レドックス・オートゴーナル標的の共ポリマーで選択的なマクロ分子電解を実証する.
  • ポリメリゼーション後の改変とポリマーの骨格分解を正確に制御する.

主な方法:

  • フタリミドとテトラクロロフタリミド (メス) アクリレットを用いてマクロモレキュルを設計する.
  • 水素原子移転やβ分裂のようなポリマー中心の急激反応を誘発するために制御された適用電圧を使用します.

主要な成果:

  • ポリメリゼーション後の改変に対する選択的電気化学的制御を達成した.
  • コポリマーのガラス化温度 (-54~125°C) を調整するための連続変換が実証されている.
  • ポリマー混合物と合成された挑戦的な共ポリマーで選択性を維持した.

結論:

  • マクロ分子電解は,選択的な材料の機能化と分解のための強力なツールを提供します.
  • ポリメリゼーション後の改変,標的分解,刺激に反応する材料の作成の可能性を拡大する.