関連する実験動画
Updated: May 22, 2025

09:25
Fabricating van der Waals Heterostructures with Precise Rotational Alignment
Published on: July 5, 2019
9.4K
ホモキラル・カーボン・ナノチューブ・ヴァン・ダー・ワールズ・クリスタル
Zhichun Zhang1, Yi Chen1, Peiyue Shen1
1Key Laboratory of Artificial Structures and Quantum Control (Ministry of Education), School of Physics and Astronomy and Tsung-Dao Lee Institute, Shanghai Jiao Tong University, Shanghai, China.
まとめ
研究者らは,六角性ボロンニトリド (hBN) 基板に高度に配列された,密度の高い半導体単面カーボンナノチューブ (SWNT) を育成する方法を開発しました. この画期的な発明により 高性能の電子機器が実現し 機動性が向上し オン/オフ比が向上しました
科学分野:
- 材料科学
- ナノテクノロジー
- 凝縮物質物理学
背景:
- 高性能の集積回路には,純粋に半導体型の単一壁の炭素ナノチューブ (SWNT) の密集した配列が必要です.
- 半導体デバイスの製造において,均一なキラリティを持つSWNTの制御された成長を達成することは依然として重要な課題です.
研究 の 目的:
- 六角性ボロン窒化物 (hBN) 基板に密集して並べられたSWNT配列の直接成長を報告する.
- hBNで製造されたSWNT配列の成長メカニズムとデバイス性能を調査する.
主な方法:
- hBN基板のSWNT配列の直接成長
- セルフアセンブリ成長メカニズムの解明のための分子ダイナミクスシミュレーション
- 成長したSWNT配列を使用してフィールド効果トランジスタ (FET) の製造と特徴付け.
主要な成果:
- hBNで高度なアラインメントと均一なキラリティを持つ密集したSWNT配列の直接成長が実証されています.
- 分子ダイナミクスのシミュレーションでは ヴァン・デル・ワールスの引力と低摩擦によって 自動組み立ての成長メカニズムが示されました
- SWNT配列から構築されたFETは,室温での高い性能: 2000cm2/Vsまでの移動性,オン/オフ比約107,および約6mA/μmの電流密度を示した.
結論:
- hBNの直接成長方法は,統合回路に適した高品質のSWNT配列の製造を可能にします.
- 自己組み立てメカニズムは,オーダーされたナノ構造の制御された成長の経路を提供します.
- SWNTベースのFETの高性能は,次世代の電子機器のためのこのアプローチの可能性を強調しています.
関連する概念動画
Network Covalent Solids
13.3K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
13.3K
Crystal Field Theory - Octahedral Complexes
25.9K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
25.9K
Chirality
22.8K
Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
22.8K
Chirality at Nitrogen, Phosphorus, and Sulfur
5.7K
Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
5.7K
Crystal Field Theory - Tetrahedral and Square Planar Complexes
41.1K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
41.1K

