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Updated: May 16, 2025

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
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Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst

Published on: April 22, 2016

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暗闇における原子移転のラジカルポリメリゼーションにおけるアミンの役割を解明する

Arman Moini Jazani1, Gorkem Yilmaz1, Mitchell Baumer1

  • 1Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States.

Journal of the American Chemical Society
|April 2, 2025
PubMed
まとめ

マルチデンテートアミンは,銅で触媒化された原子移転ラジカルポリメリゼーション (ATRP) で電子ドナーとして作用し,暗闇で制御されたポリマー合成を可能にします. これらのアミンはATRPの開始を促進し,残留空気でも堅固な性能を提供します.

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Amines to Amides: Acylation of Amines

Various carboxylic acid derivatives (such as acid chlorides, esters, and anhydrides) can be used for the acylation of amines to yield amides. The reaction requires two equivalents of amines. The first amine molecule functions as a nucleophile and attacks the carbonyl carbon to produce a tetrahedral intermediate. This is followed by the loss of the leaving group and restoration of the C=O bond.
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