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Updated: May 15, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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ケージ限定可視光触媒によって可能になった非対称なカスケード光サイクル加減-アシロイン再配置

Jie Chen1, Yu-Lin Lu1, Yongxian Huang1

  • 1GBRCE for Functional Molecular Engineering, MOE Laboratory of Bioinorganic and Synthetic Chemistry, LIFM, IGCME, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China.

Journal of the American Chemical Society
|April 8, 2025
PubMed
まとめ

化学者は,可視光誘発の非対称なカスケード反応を可能にするキラル光敏感金属有機ケージ (cPMOC) を合成した. この新しい触媒は独特のビサイクロ[3.2.1]オクタンを作り,触媒における狭い空間の重要性を示しています.

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